| Visible-Light-Active Plasmonic Ag-SrTiO3 Nanocomposites for the Degradation of NO in Air with High Selectivity | |
| Zhang, Qian1; Huang, Yu1,2; Xu, Lifeng1; Cao, Jun-ji1,2; Ho, Wingkei3; Lee, Shun Cheng4 | |
| 2016-02-17 | |
| 发表期刊 | ACS APPLIED MATERIALS & INTERFACES
 |
| 卷号 | 8期号:6页码:4165-4174 |
| 文章类型 | Article |
| 摘要 | Harnessing inexhaustible solar energy for photocatalytic disposal of nitrogen oxides is of great significance nowadays. In this study, Ag-SrTiO3 nanocomposites (Ag-STO) were synthesized via one-pot solvothermal method for the first time. The deposition of Ag nanoparticles incurs a broad plasmonic resonance absorption in the visible light range, resulting in enhanced visible light driven activity on NO removal in comparison with pristine SrTiO3. The Ag loading amount has a significant influence on light absorption properties of Ag-STO, which further affects the photocatalytic efficiency. It was shown that 0.5% Ag loading onto SrTiO3 (in mass ratio) could remove 30% of NO in a single reaction path under visible light irradiation, which is twice higher than that achieved on pristine SrTiO3. Most importantly, the generation of harmful intermediate (NO2) is largely inhibited over SrTiO3 and Ag-STO nanocomposites, which can be ascribed to the basic surface property of strontium sites. As identified by electron spin resonance (ESR) spectra, center dot O-2(-) and center dot OH radicals are the major reactive species for NO oxidation. Essentially speaking, the abundance of reactive oxygen radicals produced over Ag-STO nanocomposites are responsible for the improved photocatalytic activity. This work provides a facile and controllable route to fabricate plasmonic Ag-SrTiO3 nanocomposite photocatalyst featuring high visible light activity and selectivity for NO abatement. |
| 关键词 | Air Pollution Control Ag-srtio3 Nanocomposites Plasmonic Effect Photo Catalysis No Removal |
| WOS标题词 | Science & Technology ; Technology |
| DOI | 10.1021/acsami.5b11887 |
| 关键词[WOS] | ENHANCED PHOTOCATALYTIC ACTIVITY ; MODIFIED TIO2 PHOTOCATALYSTS ; RH-DOPED SRTIO3 ; SOLVOTHERMAL SYNTHESIS ; EFFICIENT DEGRADATION ; METAL NANOPARTICLES ; STRONTIUM-TITANATE ; ORGANIC POLLUTANT ; TITANIUM-DIOXIDE ; REMOVAL |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| WOS类目 | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| WOS记录号 | WOS:000370583100073 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.ieecas.cn/handle/361006/5828 |
| 专题 | 粉尘与环境研究室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Earth Environm, Key Lab Aerosol Chem & Phys, Xian 710061, Peoples R China 2.Chinese Acad Sci, Inst Earth Environm, SKLLQG, Xian 710061, Peoples R China 3.Hong Kong Inst Educ, Dept Sci & Environm Studies, Hong Kong, Hong Kong, Peoples R China 4.Hong Kong Polytech Univ, Dept Civil & Environm Engn, Hong Kong, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Qian,Huang, Yu,Xu, Lifeng,et al. Visible-Light-Active Plasmonic Ag-SrTiO3 Nanocomposites for the Degradation of NO in Air with High Selectivity[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(6):4165-4174. |
| APA | Zhang, Qian,Huang, Yu,Xu, Lifeng,Cao, Jun-ji,Ho, Wingkei,&Lee, Shun Cheng.(2016).Visible-Light-Active Plasmonic Ag-SrTiO3 Nanocomposites for the Degradation of NO in Air with High Selectivity.ACS APPLIED MATERIALS & INTERFACES,8(6),4165-4174. |
| MLA | Zhang, Qian,et al."Visible-Light-Active Plasmonic Ag-SrTiO3 Nanocomposites for the Degradation of NO in Air with High Selectivity".ACS APPLIED MATERIALS & INTERFACES 8.6(2016):4165-4174. |
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Visible-Light-Active（3276KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 请求全文 | |
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论