Partitioning and transformation behavior of toxic elements duringcirculated fluidized bed combustion of coal gangue
Zhou,CC(Zhou,Chuncai)[1,2,3,4]; Liu,GJ(Liu,Guijian)[1,2]; Fang,T(Fang,Ting)[1]; Wu,D(Wu,Dun)[1]; Lam,PKS(Lam,Paul Kwan Sing)[3,4]
2014-06-25
发表期刊Fuel
卷号135页码:1-8
文章类型期刊论文
摘要

A study on toxic elements behaviors from a 330 MW coal gangue circulated fluidized bed co-combustion power plant equipped with electrostatic precipitators (ESPs) was performed. Simultaneous sampling of feed coal, bottom ash, fly ash and flue gas were implemented. Sequential chemical extraction was taken to investigate the transformation behaviors of toxic elements. The relative distribution and partitioning behavior of toxic elements in the power plants were analyzed systemically. The toxic elements can be divided into two groups, Cluster one, whereby high volatile tendencies are represented by As, Cd, Cu, Pb, Se and Sn which have a volatilization ratio more than 20% and are mainly enriched in fly ash. These elements are primarily associated with sulfide minerals. Cluster two, represented by Co, Cr, Mn and V, have low volatilization rate (65%) and are equally distributed between bottom ash and fly ash. In addition, Bi, Ni and Zn may be located between Cluster one and Cluster two. The variation of modes of occurrence of toxic elements could lead to the difference of transformation behaviors during the combustion of feed coal. Most toxic elements transformed and partitioned into other fractions from Fe–Mn oxides during combustion.

关键词Coal Gangue Mineralogy Toxic Elements Partitioning Transformation Behavior
DOI10.1016/j.fuel.2014.06.034
收录类别SCI
语种英语
引用统计
被引频次:85[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ieecas.cn/handle/361006/9877
专题黄土与第四纪地质国家重点实验室(2010~)
通讯作者Liu,GJ(Liu,Guijian)[1,2]
作者单位1.CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui 230026, China;
2.State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xi’an, Shaanxi 710075, China;
3.State Key Laboratory in Marine Pollution, Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China;
4.University of Science and Technology of China – City University of Hong Kong Joint Advanced Research Centre, Suzhou, Jiangsu 251006, China
推荐引用方式
GB/T 7714
Zhou,CC,Liu,GJ,Fang,T,et al. Partitioning and transformation behavior of toxic elements duringcirculated fluidized bed combustion of coal gangue[J]. Fuel,2014,135:1-8.
APA Zhou,CC,Liu,GJ,Fang,T,Wu,D,&Lam,PKS.(2014).Partitioning and transformation behavior of toxic elements duringcirculated fluidized bed combustion of coal gangue.Fuel,135,1-8.
MLA Zhou,CC,et al."Partitioning and transformation behavior of toxic elements duringcirculated fluidized bed combustion of coal gangue".Fuel 135(2014):1-8.
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