Optical property variations from a precursor (isoprene) to its atmospheric oxidation products | |
Zeng, YL (Zeng, Yaling)[ 1,2 ]; Shen, ZX (Shen, Zhenxing)[ 1,2 ]; Zhang, T (Zhang, Tian)[ 1 ]; Lu, D (Lu, Di)[ 1 ]; Li, GH (Li, Guohui)[ 2 ]; Lei, YL (Lei, Yali)[ 1 ]; Feng, T (Feng, Tian)[ 2 ]; Wang, X (Wang, Xin)[ 3 ]; Huang, Y (Huang, Yu)[ 2 ]; Zhang, Q (Zhang, Qian)[ 1 ]; Xu, HM (Xu, Hongmei)[ 1 ]; Wang, QY (Wang, Qiyuan)[ 2 ]; Cao, JJ (Cao, Junji)[ 2 ] | |
通讯作者 | Shen, Zhenxing(zxshen@mail.xjtu.edu.cn) |
2018-11 | |
发表期刊 | ATMOSPHERIC ENVIRONMENT |
ISSN | 1352-2310 |
卷号 | 193页码:198-204 |
文章类型 | 期刊论文 |
摘要 | Isoprene is a crucial precursor of secondary organic aerosols (SOAs) that reacts with radicals or oxidants such as OH, O3, and NO3. The reaction mechanisms under various conditions have been elucidated through years of research. In this study, the UV–vis light absorptive ability of oxydates for isoprene was calculated at the PBE1PBE/6-311g (d) level using Gaussian 09. The results indicated that reactions of isoprene with OH and O3 would produce less absorptive organics; the intensity of the absorption peaks and the maximum absorption wavelength decreased relative to those of the precursor. The oxydates formed from isoprene through an NO3-initiated reaction had different light absorption properties. The optical properties of the oxydates exhibited a bathochromic shift and hyperchromic effect relative to those of the precursor. NO3 mainly originated from vehicular traffic, indicating that anthropogenic activity heavily affected the formation of oxydates and light absorption. The light absorption properties and irradiation effect of SOAs caused by isoprene heavily depended on the reaction route. Transformation of functional groups was the dominated factor in photobleaching and photoenhancement of oxidative products. This study provides a detailed mechanism that explains the changes in optical absorption properties during isoprene oxidation. |
关键词 | Isoprene Hydroxyl Radical Ozone No3 Optical Property Quantum Chemistry Calculation |
DOI | 10.1016/j.atmosenv.2018.09.017 |
关键词[WOS] | SECONDARY ORGANIC AEROSOL ; BROWN CARBON ; PHOTOOXIDATION ; MODEL ; OZONOLYSIS ; MECHANISM ; YIELDS ; NO3 ; SIMULATIONS ; NITRATES |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[41573101] ; National Natural Science Foundation of China[41877383] ; Natural Science Foundation of Shaanxi Province, China[2016ZDJC-22] ; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, China[SKLLQG1616] |
WOS研究方向 | Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences |
项目资助者 | National Natural Science Foundation of China ; Natural Science Foundation of Shaanxi Province, China ; State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, China |
WOS类目 | Environmental Sciences ; Meteorology & Atmospheric Sciences |
WOS记录号 | WOS:000448091600020 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ieecas.cn/handle/361006/9583 |
专题 | 粉尘与环境研究室 |
通讯作者 | Shen, ZX (Shen, Zhenxing)[ 1,2 ] |
作者单位 | 1.Department of Environmental Sciences and Engineering, Xi'an Jiaotong University, Xi'an, 710049, China; 2.Key Lab of Aerosol Chemistry & Physics, SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, China; 3.Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, 55128, Germany |
推荐引用方式 GB/T 7714 | Zeng, YL ,Shen, ZX ,Zhang, T ,et al. Optical property variations from a precursor (isoprene) to its atmospheric oxidation products[J]. ATMOSPHERIC ENVIRONMENT,2018,193:198-204. |
APA | Zeng, YL .,Shen, ZX .,Zhang, T .,Lu, D .,Li, GH .,...&Cao, JJ .(2018).Optical property variations from a precursor (isoprene) to its atmospheric oxidation products.ATMOSPHERIC ENVIRONMENT,193,198-204. |
MLA | Zeng, YL ,et al."Optical property variations from a precursor (isoprene) to its atmospheric oxidation products".ATMOSPHERIC ENVIRONMENT 193(2018):198-204. |
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1-s2.0-S135223101830(1642KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 请求全文 |
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