| Carbonaceous aerosols in megacity Xi'an, China: Implications of thermal/optical protocols comparison | |
| Han, Y. M.1,2,3; Chen, L. -W. A.4,5; Huang, R. -J.1,2,6; Chow, J. C.1,2,5; Watson, J. G.1,2,5; Ni, H. Y.1,2; Liu, S. X.1,2; Fung, K. K.7; Shen, Z. X.3; Wei, C.1,2,8; Wang, Q. Y.1,2; Tian, J.1,2; Zhao, Z. Z.1,2; Prevot, Andre S. H.1,2,6; Cao, J. J.1,2 | |
| 2016-05-01 | |
| 发表期刊 | ATMOSPHERIC ENVIRONMENT
 |
| 卷号 | 132期号:2016页码:58-68 |
| 文章类型 | Article |
| 摘要 | Carbonaceous aerosol is an important component that influences the environment, climate, and human health. Organic and elemental carbon (OC and EC) are the two main constituents of carbonaceous aerosols that have opposite, i.e., cooling versus warming, effects on the Earth's radiation balance. Knowledge on the variability of OC/EC splits measured by different thermal/optical protocols is useful for understanding the uncertainty in the climate models. This study shows good correlations within OC or EC (r(2) > 0.83, P < 0.001) across the IMPROVE, IMPROVE_A, and EUSAAR_2 protocols for both ambient aerosol samples and biomass burning samples. However, EC concentrations differ by more than two folds, and OC/EC ratios differ up to a factor of 2.7. The discrepancies were attributed to the selection between the reflectance and transmittance corrections and the different peak inert-atmosphere temperature. The IMPROVE and IMPROVE_A protocols also quantified different char and soot concentrations, two subtypes of EC with distinct chemical and optical properties. Char, but not soot, was found to correlate with the humic-like substances (HULIS) content in the samples, suggesting that both char and HULLS originate mainly from biomass burning. A one-year (2012-2013) ambient aerosol monitoring in Xi'an, China, shows that OC, EC, and char displayed winter highs and summer lows, while soot had no seasonal trend. The char/soot ratios showed a "single peak" in winter, while OC/EC ratios exhibited "dual peak" feature due to the influence of secondary organic aerosol formation. In addition to commonly measured OC and EC, we recommend both char and soot from a common reference method to be considered in the chemical transport and climate models. (C) 2016 Elsevier Ltd. All rights reserved. |
| 关键词 | Thermal/optical Protocols Carbonaceous Aerosols Organic And Elemental Carbon Measurement Char And Soot Biomass Burning Emissions Temporal Variations Climatic Implications |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences |
| DOI | 10.1016/j.atmosenv.2016.02.023 |
| 关键词[WOS] | HUMIC-LIKE SUBSTANCES ; DIFFERENT TEMPERATURE PROTOCOLS ; RIVER DELTA REGION ; BLACK CARBON ; ELEMENTAL CARBON ; ORGANIC AEROSOLS ; MIXING STATE ; AIR-QUALITY ; URBAN ; REFLECTANCE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences |
| WOS类目 | Environmental Sciences ; Meteorology & Atmospheric Sciences |
| WOS记录号 | WOS:000374614500007 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.ieecas.cn/handle/361006/5764 |
| 专题 | 粉尘与环境研究室 |
| 作者单位 | 1.Chinese Acad Sci, SKLLQG, Xian 710061, Peoples R China 2.Chinese Acad Sci, Key Lab Aerosol Chem & Phys, Inst Earth Environm, Xian 710061, Peoples R China 3.Xi An Jiao Tong Univ, Sch Human Settlements & Civil Engn, Xian 710049, Peoples R China 4.Univ Nevada, Dept Environm & Occupat Hlth, Las Vegas, NV 89154 USA 5.Desert Res Inst, Div Atmospher Sci, 2215 Raggio Pkwy, Reno, NV 89512 USA 6.Paul Scherrer Inst, Lab Atmospher Chem, CH-5232 Villigen, Switzerland 7.AtmAA Inc, 23917 Craftsman Rd, Calabasas, CA 91302 USA 8.Chinese Acad Sci, Shanghai Adv Res Inst, SCDRC, Shanghai 201210, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Y. M.,Chen, L. -W. A.,Huang, R. -J.,et al. Carbonaceous aerosols in megacity Xi'an, China: Implications of thermal/optical protocols comparison[J]. ATMOSPHERIC ENVIRONMENT,2016,132(2016):58-68. |
| APA | Han, Y. M..,Chen, L. -W. A..,Huang, R. -J..,Chow, J. C..,Watson, J. G..,...&Cao, J. J..(2016).Carbonaceous aerosols in megacity Xi'an, China: Implications of thermal/optical protocols comparison.ATMOSPHERIC ENVIRONMENT,132(2016),58-68. |
| MLA | Han, Y. M.,et al."Carbonaceous aerosols in megacity Xi'an, China: Implications of thermal/optical protocols comparison".ATMOSPHERIC ENVIRONMENT 132.2016(2016):58-68. |
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| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Carbonaceous aerosol（2162KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 请求全文 | |
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