Salt-assisted Synthesis of Hollow Bi2WO6 Microspheres with Superior Photocatalytic Activity for NO Removal | |
Chen, Meijuan1; Huang, Yu2,3; Lee, Shun Cheng4 | |
2017-02-01 | |
发表期刊 | CHINESE JOURNAL OF CATALYSIS |
卷号 | 38期号:2页码:348-356 |
文章类型 | Article |
摘要 | Hollow Bi(2)W0(6) microspheres are successfully synthesized by a facile ultrasonic spray pyrolysis (USP) method using NaCl as a salt template. The as-prepared hollow microspheres assembled as nanoplates with dimensions of approximately 41-148 nm and are dispersed with non-uniform pores on the template surface. By swapping the salt template with KC1 or Na2SO4, different morphologies of Bi(2)W0(6) are obtained. The experimental results demonstrate that NaCI plays a key role on the formation of Bi(2)W0(6) with hollow structures. The specific growth mechanism of hollow microspheres was studied in detail. The Bi(2)W0(6) hollow microspheres exhibit an excellent photocatalytic efficiency for NO removal under solar light irradiation, which is 1.73 times higher than for the Bi(2)W0(6) obtained in the absence of any salt template. This enhancement can be ascribed to the simultaneous improvement on the surface area and visible light -harvesting ability from the hollow structures. Electron spin resonance (ESR) results suggest that both radicals of "OH and O-2-are involved in the photocatalytic process over the BWO-NaC1 sample. The production of O-2 radicals offers better durability for NO removal. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
关键词 | Ultrasonic Spray Pyrolysis Salt Template Bi2wo6 Hollow Microsphere No Removal |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/S1872-2067(16)62584-6 |
关键词[WOS] | ULTRASONIC SPRAY-PYROLYSIS ; SOLID-SOLUTION PHOTOCATALYSTS ; VISIBLE-LIGHT ; DIFFERENT MORPHOLOGIES ; THIN-FILMS ; INDOOR AIR ; PHOTODEGRADATION ; NANOSTRUCTURES ; NANOCRYSTALS ; FABRICATION |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Chemistry ; Engineering |
WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
WOS记录号 | WOS:000396384300019 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ieecas.cn/handle/361006/5514 |
专题 | 粉尘与环境研究室 |
作者单位 | 1.Xi An Jiao Tong Univ, Sch Human Settlements & Civil Engn, Xian 710049, Shaanxi, Peoples R China 2.Chinese Acad Sci, Inst Earth Environm, Key Lab Aerosol Chem & Phys, Xian 710061, Shaanxi, Peoples R China 3.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol SKLLQG, Xian 710061, Shaanxi, Peoples R China 4.Hong Kong Polytech Univ, Dept Civil & Environm Engn, Hong Kong, Hong Kong, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Meijuan,Huang, Yu,Lee, Shun Cheng. Salt-assisted Synthesis of Hollow Bi2WO6 Microspheres with Superior Photocatalytic Activity for NO Removal[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(2):348-356. |
APA | Chen, Meijuan,Huang, Yu,&Lee, Shun Cheng.(2017).Salt-assisted Synthesis of Hollow Bi2WO6 Microspheres with Superior Photocatalytic Activity for NO Removal.CHINESE JOURNAL OF CATALYSIS,38(2),348-356. |
MLA | Chen, Meijuan,et al."Salt-assisted Synthesis of Hollow Bi2WO6 Microspheres with Superior Photocatalytic Activity for NO Removal".CHINESE JOURNAL OF CATALYSIS 38.2(2017):348-356. |
条目包含的文件 | ||||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
Salt-assisted Synthe(1526KB) | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 请求全文 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论