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Barium isotopic composition of the upper continental crust
Nan, Xiao-Yun1; Yu, Hui-Min1; Rudnick, Roberta L.2,3; Gaschnig, Richard M.4; Xu, Juan1; Li, Wang-Ye1; Zhang, Qun1; Jin, Zhang-Dong5; Li, Xian-Hua6; Huang, Fang1
2018-07-15
发表期刊GEOCHIMICA ET COSMOCHIMICA ACTA
卷号233期号:5页码:33-49
文章类型Article
摘要The upper continental crust (UCC) is an important reservoir of Ba within the Earth. We report high precision (<=+/- 0.05 parts per thousand, 2SD) Ba isotopic data for 71 samples (including granites, granodiorites, loess, glacial diamictites, and river sediments) to constrain the Ba isotopic composition of the UCC. I-type granites from the Fogang batholith, Southeastern (SE) China, exhibit variable delta Ba-137/134 (-0.16 parts per thousand to 0.01 parts per thousand), which may be due to isotopic fractionation during the latest stages of magmatic differentiation. The delta Ba-137/134 of S-type granites from Darongshan-Shiwandashan, SE China (-0.03 parts per thousand to 0.11 parts per thousand) correlate with epsilon(Nd) (t), likely reflecting mixing of heterogeneous crustal source materials. Five A-type granites with high SiO2 contents (similar to 76 wt%) from Nankunshan, SE China have remarkably low delta Ba-137/134 (-0.47 parts per thousand to -0.33 parts per thousand), which possibly arose from magmatic differentiation or assimilation of crustal materials with light Ba isotopic compositions. Loess from northwestern China has homogeneous delta Ba-137/134 (-0.02 parts per thousand to 0.03 parts per thousand) that shows no correlation with bulk compositions, sample locations, or degree of chemical weathering, suggesting that loess is representative of the average Ba isotopic composition of the UCC. Three river sediments from northern China have delta Ba-137/134 similar to that of loess. The delta Ba-137/134 of glacial diamictites vary with CIA values: those with high CIA (>= 60) have heterogeneous delta Ba-137/134 (-0.19 parts per thousand to 0.35 parts per thousand), while those with low CIA (<60) have delta Ba-137/134 around 0 parts per thousand, identical to the values of loess and river sediments, suggesting that Ba isotopes can be fractionated during chemical weathering. In all, samples from the UCC have highly heterogeneous delta Ba-137/134, ranging from -0.47 parts per thousand to 0.35 parts per thousand. Using the weighted average of samples in this study, the delta Ba-137/134 of the UCC is estimated to be 0.00 +/- 0.03 parts per thousand (2SD/root n, n = 71), which is similar to the average Ba isotopic composition of the upper mantle, but significantly lower than delta Ba-137/134 of seawater. (C) 2018 Elsevier Ltd. All rights reserved.
关键词Barium Isotopes Granites Loess Glacial Diamictites River Sediments
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.gca.2018.05.004
关键词[WOS]ANCIENT GLACIAL DIAMICTITES ; PLASMA-MASS SPECTROMETRY ; LACHLAN FOLD BELT ; CHEMICAL-COMPOSITION ; CHINESE LOESS ; ICP-MS ; STABLE-ISOTOPES ; SILICATE MELTS ; TRACE-ELEMENTS ; FE ISOTOPES
收录类别SCI
WOS研究方向Geochemistry & Geophysics
WOS类目Geochemistry & Geophysics
WOS记录号WOS:000433900000003
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被引频次:71[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ieecas.cn/handle/361006/5148
专题加速器质谱中心
作者单位1.Univ Sci & Technol China, Sch Earth & Space Sci, CAS Key Lab Crust Mantle Mat & Environm, Hefei 230026, Anhui, Peoples R China
2.Univ Calif Santa Barbara, Dept Earth Sci, Santa Barbara, CA 93106 USA
3.Univ Calif Santa Barbara, Earth Res Inst, Santa Barbara, CA 93106 USA
4.Univ Massachusetts Lowell, Dept Environm Earth & Atmospher Sci, Lowell, MA 01854 USA
5.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian 710075, Shaanxi, Peoples R China
6.Chinese Acad Sci, Inst Geol & Geophys, Beijing 100029, Peoples R China
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Nan, Xiao-Yun,Yu, Hui-Min,Rudnick, Roberta L.,et al. Barium isotopic composition of the upper continental crust[J]. GEOCHIMICA ET COSMOCHIMICA ACTA,2018,233(5):33-49.
APA Nan, Xiao-Yun.,Yu, Hui-Min.,Rudnick, Roberta L..,Gaschnig, Richard M..,Xu, Juan.,...&Huang, Fang.(2018).Barium isotopic composition of the upper continental crust.GEOCHIMICA ET COSMOCHIMICA ACTA,233(5),33-49.
MLA Nan, Xiao-Yun,et al."Barium isotopic composition of the upper continental crust".GEOCHIMICA ET COSMOCHIMICA ACTA 233.5(2018):33-49.
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