<p>Carbon dioxide activated biochar-clay mineral composite efficiently removes ciprofloxacin from contaminated water - Reveals an incubation study</p>

doi:10.1016/j.jclepro.2021.130079

IEECAS OpenIR > 黄土与第四纪地质国家重点实验室（2010~）

	Carbon dioxide activated biochar-clay mineral composite efficiently removes ciprofloxacin from contaminated water - Reveals an incubation study
	Arif, Muhammad 1,4; Liu, Guijian 1,2; Rehman, Muhammad Zia ur 3; Yousaf, Balal 1,5; Ahmed, Rafay 1; Miana, Md Manik 1; Ashrafa, Aniqa 1; Munirf, Mehr Ahmed Mujtaba 6; Rashida, Muhammad Saqib 1; Naeem, Asif 7
通讯作者	Liu, Guijian(lgj@ustc.edu.cn)
	2022-01-15
发表期刊	JOURNAL OF CLEANER PRODUCTION
ISSN	0959-6526
卷号	332 页码:14
摘要	Ciprofloxacin, a second-generation synthetic fluoroquinolone derivative widely used in human and veterinary medicines, has the potential to pose a serious risk to aquatic organisms and humans. The current research investigated the removal of ciprofloxacin using biochar treated with clay mineral and subsequently activated with carbon dioxide (CO2) produced at two different pyrolysis temperatures (350 and 650 C). Batch adsorption experiments were carried out to assess the removal efficiency of ciprofloxacin by as-synthesized materials. The effects of various factors, such as pH, contact time, adsorbent dose, initial ciprofloxacin concentration, and temperature were studied during the removal process. The physicochemical characterization results verified the successful loading of clay minerals on biochar. Non-linear adsorption models were employed to understand the nature of adsorption processes however, the Pseudo-second-order kinetic and Freudlich and Redlich Peterson isotherm models best fitted with the adsorption data. These findings indicated that the adsorption did not follow an ideal monolayer adsorption suggesting hybrid chemical adsorption process that was spontaneous and endothermic. The maximum adsorption (50.32 mg g(-1)) of ciprofloxacin was achieved by CO2 activated biochar-clay mineral composite prepared at 350 C, and was almost two times higher than the pristine biochar at neutral pH and 40 C. The possible proposed mechanisms involved for the removal of ciprofloxacin were electrostatic attraction, cation exchange, pore-filling effect, and 7C-7C interactions. Our findings demonstrate that application of CO2 activated biochar-clay mineral composite is a promising technique for efficient removal of ciprofloxacin from aqueous solution.
关键词	Biochar Clay minerals Composites Ciprofloxacin Biochar activation Adsorption
DOI	10.1016/j.jclepro.2021.130079
关键词[WOS]	AQUEOUS-SOLUTION ; RICE HUSK ; ADSORPTION ; MONTMORILLONITE ; PYROLYSIS ; CARBON ; ANTIBIOTICS ; MECHANISMS ; RESIDUES ; AMMONIUM
收录类别	SCI ; SCI
语种	英语
资助项目	National Key Research and Development Project of China[2020YFC1908601] ; National Key Research and Development Project of China[2020YFC1908602]
WOS研究方向	Science & Technology - Other Topics ; Engineering ; Environmental Sciences & Ecology
项目资助者	National Key Research and Development Project of China
WOS类目	Green & Sustainable Science & Technology ; Engineering, Environmental ; Environmental Sciences
WOS记录号	WOS:000770361900005
出版者	ELSEVIER SCI LTD
引用统计	被引频次：23[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.ieecas.cn/handle/361006/17632
专题	黄土与第四纪地质国家重点实验室（2010~）
通讯作者	Liu, Guijian
作者单位	1.Univ Sci & Technol China, Sch Earth & Space Sci, CAS Key Lab Crust Mantle Mat & Environm, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian 710075, Shaanxi, Peoples R China 3.Univ Agr Faisalabad, Inst Soil & Environm Sci, Faisalabad 38040, Pakistan 4.Muhammad Nawaz Shareef Univ Agr, Dept Soil & Environm Sci, Multan, Pakistan 5.Middle East Tech Univ, Dept Environm Engn, TR-06800 Ankara, Turkey 6.Zhejiang Univ, Minist Educ MOE Key Lab Environm Remediat & Eco, Inst Crop Sci & Zhejiang Key Lab Crop Germplasm, Coll Environm & Resources Sci, Hangzhou 310058, Peoples R China 7.Nucl Inst Agr & Biol NIAB, Jhang Rd, Faisalabad 38000, Pakistan
推荐引用方式 GB/T 7714	Arif, Muhammad,Liu, Guijian,Rehman, Muhammad Zia ur,et al. Carbon dioxide activated biochar-clay mineral composite efficiently removes ciprofloxacin from contaminated water - Reveals an incubation study [J]. JOURNAL OF CLEANER PRODUCTION,2022,332:14.
APA	Arif, Muhammad.,Liu, Guijian.,Rehman, Muhammad Zia ur.,Yousaf, Balal.,Ahmed, Rafay.,...&Naeem, Asif.(2022). Carbon dioxide activated biochar-clay mineral composite efficiently removes ciprofloxacin from contaminated water - Reveals an incubation study .JOURNAL OF CLEANER PRODUCTION,332,14.
MLA	Arif, Muhammad,et al." Carbon dioxide activated biochar-clay mineral composite efficiently removes ciprofloxacin from contaminated water - Reveals an incubation study ".JOURNAL OF CLEANER PRODUCTION 332(2022):14.