Comparison and Calibration of Elemental Measurements in Sediments Using X-Ray Fluorescence Core Scanning with ICP Methods: A Case Study of the South China Sea Deep Basin

doi:10.1007/s11802-021-4554-1

IEECAS OpenIR > 黄土与第四纪地质国家重点实验室（2010~）

	Comparison and Calibration of Elemental Measurements in Sediments Using X-Ray Fluorescence Core Scanning with ICP Methods: A Case Study of the South China Sea Deep Basin
	Xu Fangjian 1,2; Hu Bangqi 2,3,4; Wang Chen 1; Zhao Jingtao 2,3; Wang Feifei 2,3; Ding Xue 2,3; Li Qing 2,3; Guo Jianwei 2,3
通讯作者	Hu Bangqi(bangqihu@gmail.com)
	2021-08-01
发表期刊	JOURNAL OF OCEAN UNIVERSITY OF CHINA
ISSN	1672-5182
卷号	20 期号:4 页码:848-856
摘要	The X-ray fluorescence (XRF) core scanning method is widely applied in studies of sedimentary paleoenvironments due to its convenient pretreatment, nondestructive characteristics, fast execution, continuous scanning, and high resolution. XRF core scanning for sediments is commonly used in the studies on the South China Sea. This study compares XRF-scanned intensities and measured inductively coupled plasma (ICP) elemental contents of core CS11 in the northeast South China Sea deep basin. The results show that the analyzed elements can be separated into three classes. Class I includes elements with high correlation coefficients, such as Ca, Sr, and Zr; Class II contains elements with average correlation coefficients, such as Fe, Mn, Ti, and Cu; and Class III comprises elements with low correlation coefficients, such as K, Ni, Zn, Rb, and Al. In the South China Sea deep basin, pore water, compaction, and grain size have weak effects on the elemental intensities and contents of short core sediments. Hence, for elements with high correlation coefficients, a linear relationship model can be established by the least-squares method, in which the converted XRF intensities are approximately equal to the measured ICP contents. Based on the established log-ratio calibration model, the resulting ln(K/Ca), ln(Ti/Ca), ln(Fe/Ca), and ln(Zr/Ca) values generally display the same variation trends as the measured curves. The elemental contents and ratios produced by the linear model via the least-squares method and the log-ratio calibration model are expected to provide high-resolution data support for future paleoenvironmental research on the South China Sea deep basin.
关键词	sediment XRF core scanning element deep sea South China Sea
DOI	10.1007/s11802-021-4554-1
关键词[WOS]	MARINE-SEDIMENTS ; XRF-SCANNER ; RIVER ; PALEOCEANOGRAPHY ; CLIMATE ; RECORDS
收录类别	SCI ; SCI
语种	英语
WOS研究方向	Oceanography
WOS类目	Oceanography
WOS记录号	WOS:000674075800010
出版者	OCEAN UNIV CHINA
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.ieecas.cn/handle/361006/16850
专题	黄土与第四纪地质国家重点实验室（2010~）
通讯作者	Hu Bangqi
作者单位	1.China Univ Petr, Sch Geosci, Qingdao 266580, Peoples R China 2.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Mineral Resources, Qingdao 266071, Peoples R China 3.Minist Nat Resources, Qingdao Inst Marine Geol, Qingdao 266071, Peoples R China 4.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian 710075, Peoples R China
推荐引用方式 GB/T 7714	Xu Fangjian,Hu Bangqi,Wang Chen,et al. Comparison and Calibration of Elemental Measurements in Sediments Using X-Ray Fluorescence Core Scanning with ICP Methods: A Case Study of the South China Sea Deep Basin[J]. JOURNAL OF OCEAN UNIVERSITY OF CHINA,2021,20(4):848-856.
APA	Xu Fangjian.,Hu Bangqi.,Wang Chen.,Zhao Jingtao.,Wang Feifei.,...&Guo Jianwei.(2021).Comparison and Calibration of Elemental Measurements in Sediments Using X-Ray Fluorescence Core Scanning with ICP Methods: A Case Study of the South China Sea Deep Basin.JOURNAL OF OCEAN UNIVERSITY OF CHINA,20(4),848-856.
MLA	Xu Fangjian,et al."Comparison and Calibration of Elemental Measurements in Sediments Using X-Ray Fluorescence Core Scanning with ICP Methods: A Case Study of the South China Sea Deep Basin".JOURNAL OF OCEAN UNIVERSITY OF CHINA 20.4(2021):848-856.