Sulfate formation is dominated by manganese-catalyzed oxidation of SO2 on aerosol surfaces during haze events

doi:10.1038/s41467-021-22091-6

IEECAS OpenIR > 粉尘与环境研究室

	Sulfate formation is dominated by manganese-catalyzed oxidation of SO2 on aerosol surfaces during haze events
	Wang, Weigang 1,2; Liu, Mingyuan 1,2; Wang, Tiantian 3; Song, Yu 3; Zhou, Li 1; Cao, Junji 4; Hu, Jingnan 5; Tang, Guigang 6; Chen, Zhe 7; Li, Zhijie 8; Xu, Zhenying 3; Peng, Chao 1; Lian, Chaofan 1; Chen, Yan 1; Pan, Yuepeng 8; Zhang, Yunhong 7; Sun, Yele 8; Li, Weijun 9; Zhu, Tong 3; Tian, Hezhong 10; Ge, Maofa 1,2
通讯作者	Song, Yu(songyu@pku.edu.cn) ; Ge, Maofa(gemaofa@iccas.ac.cn)
	2021-03-31
发表期刊	NATURE COMMUNICATIONS
ISSN	2041-1723
卷号	12 期号:1 页码:10
摘要	The formation mechanism of aerosol sulfate during wintertime haze events in China is still largely unknown. As companions, SO2 and transition metals are mainly emitted from coal combustion. Here, we argue that the transition metal-catalyzed oxidation of SO2 on aerosol surfaces could be the dominant sulfate formation pathway and investigate this hypothesis by integrating chamber experiments, numerical simulations and in-field observations. Our analysis shows that the contribution of the manganese-catalyzed oxidation of SO2 on aerosol surfaces is approximately one to two orders of magnitude larger than previously known routes, and contributes 69.2%5.0% of the particulate sulfur production during haze events. This formation pathway could explain the missing source of sulfate and improve the understanding of atmospheric chemistry and climate change. Sulfate aerosols are an important component of wintertime haze events in China, but their production mechanisms are not well known. Here, the authors show that transition metal-catalyzed oxidation of SO2 on aerosol surfaces could be the dominant sulfate formation pathway in Northern China.
DOI	10.1038/s41467-021-22091-6
收录类别	SCI ; SCI
语种	英语
资助项目	National Natural Science Foundation of China ; National Key Research and Development Program of China[41822703] ; National Key Research and Development Program of China[2017YFC0209500] ; National Natural Science Foundation of China[91644212] ; National Natural Science Foundation of China[91544227] ; National Natural Science Foundation of China[91844301] ; National research program for key issues in air pollution control[DQGG-0103] ; Beijing National Laboratory for Molecular Sciences[BNLMS-CXXM-202011]
WOS研究方向	Science & Technology - Other Topics
项目资助者	National Natural Science Foundation of China ; National Key Research and Development Program of China ; National Natural Science Foundation of China ; National research program for key issues in air pollution control ; Beijing National Laboratory for Molecular Sciences
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:000636879000014
出版者	NATURE RESEARCH
引用统计	被引频次：134[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.ieecas.cn/handle/361006/16309
专题	粉尘与环境研究室
通讯作者	Song, Yu; Ge, Maofa
作者单位	1.Chinese Acad Sci, CAS Res Educ Ctr Excellence Mol Sci, Inst Chem, Beijing Natl Lab Mol Sci BNLMS,State Key Lab Stru, Beijing, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China 3.Peking Univ, Dept Environm Sci, State Key Joint Lab Environm Simulat & Pollut Con, Beijing, Peoples R China 4.Chinese Acad Sci, Inst Earth Environm, Key Lab Aerosol Chem & Phys, State Key Lab Loess & Quaternary Geol, Xian, Shaanxi, Peoples R China 5.Chinese Res Inst Environm Sci, Inst Atmospher Environm, Beijing, Peoples R China 6.China Natl Environm Monitoring Ctr, State Environm Protect Key Lab Qual Control Envir, Beijing, Peoples R China 7.Beijing Inst Technol, Sch Chem & Chem Engn, Inst Chem Phys, Beijing, Peoples R China 8.Chinese Acad Sci, Inst Atmospher Phys, State Key Lab Atmospher Boundary Layer Phys & Atm, Beijing, Peoples R China 9.Zhejiang Univ, Sch Earth Sci, Dept Atmospher Sci, Hangzhou, Peoples R China 10.Beijing Normal Univ, Sch Environm, State Key Joint Lab Environm Simulat & Pollut Con, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Wang, Weigang,Liu, Mingyuan,Wang, Tiantian,et al. Sulfate formation is dominated by manganese-catalyzed oxidation of SO2 on aerosol surfaces during haze events[J]. NATURE COMMUNICATIONS,2021,12(1):10.
APA	Wang, Weigang.,Liu, Mingyuan.,Wang, Tiantian.,Song, Yu.,Zhou, Li.,...&Ge, Maofa.(2021).Sulfate formation is dominated by manganese-catalyzed oxidation of SO2 on aerosol surfaces during haze events.NATURE COMMUNICATIONS,12(1),10.
MLA	Wang, Weigang,et al."Sulfate formation is dominated by manganese-catalyzed oxidation of SO2 on aerosol surfaces during haze events".NATURE COMMUNICATIONS 12.1(2021):10.