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Provenance of Fe in Chinese Deserts: Evidence from the geochemistry and mineralogy of soil particles
He, Tong1; Sun, Youbin2; Gray, Jessica3; Gu, Ying3
通讯作者He, Tong(hetong@nuist.edu.cn)
2021-03-01
发表期刊CATENA
ISSN0341-8162
卷号198页码:9
摘要Determining the categories and content of Fe containing silicate minerals in the desert soils and sediments of northern China is important for understanding the Fe cycle and for correctly interpreting the paleoenvironmental signals from the Loess Plateau downwind. Using a mineral liberation analyzer (MLA), we established the modal mineral abundances of a complete set of Fe containing mineral species in the fine sand to silt fractions of surface samples from Chinese deserts. Results show that the most common discrete particles containing Fe are the silicate phases (similar to 15 wt%), while the weathering product (i.e., Fe oxides) phases are minor and their abundances vary greatly (0.38-4.15 wt%). The degree of weathering has a substantial particle size dependence. The fine fraction (5-20 mu m) generally has a relatively low Fe/Si ratio, possibly due to weathering, while the Fe/Si ratio of the coarse fractions (20-45 mu m, 45-63 mu m, 63-75 mu m, and >75 mu m) are relatively invariant. Abundant Fe is contained within the coarse fractions, which are associated with the local geology. The strong relationship between the Fe and Mg bound within the silicate phases further supports the conclusion that the correlated deviations in the Fe/Si and Mg/Si ratios originate from the provenance bedrock (i.e., siliciclastic, low-grade metamorphic, and possibly high-grade metamorphic, rocks). Since Mg tends to be easily removed during weathering, the Fe/Mg ratios of silicate species largely reflect the weathering intensity. We used the regression equation for the relationship between the local precipitation amount and the Fe/Mg ratios of the soils to produce a novel precipitation proxy. Compared with classical provenance studies conducted using coarse sand and larger rock fragments, the MLA methodology is more applicable to the fine sand and silt fractions; thus, it contributes to the development of weathering and provenance indices based on geochemistry and mineralogy.
关键词Fe provenance Fe speciation Fe/Mg ratio Fe-Mg substitution Precipitation proxy Asian monsoon Desert-loess transitional zone
DOI10.1016/j.catena.2020.105053
关键词[WOS]CHEMICAL-WEATHERING HISTORY ; NORTHERN CHINA ; LOESS PLATEAU ; MA ; EVOLUTION ; DEPOSITS ; SEM ; TEM
收录类别SCI ; SCI
语种英语
资助项目National Science Foundation of China[41877284] ; National Science Foundation of China[41303071]
WOS研究方向Geology ; Agriculture ; Water Resources
项目资助者National Science Foundation of China
WOS类目Geosciences, Multidisciplinary ; Soil Science ; Water Resources
WOS记录号WOS:000605337000050
出版者ELSEVIER
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ieecas.cn/handle/361006/15889
专题古环境研究室
通讯作者He, Tong
作者单位1.Nanjing Univ Informat Sci & Technol, Sch Geog Sci, Nanjing 210044, Peoples R China
2.Chinese Acad Sci, Inst Earth Environm, Xian 710061, Peoples R China
3.Queensland Univ, Julius Kruttschnitt Mineral Res Ctr JKMRC, Brisbane, Qld, Australia
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GB/T 7714
He, Tong,Sun, Youbin,Gray, Jessica,et al. Provenance of Fe in Chinese Deserts: Evidence from the geochemistry and mineralogy of soil particles[J]. CATENA,2021,198:9.
APA He, Tong,Sun, Youbin,Gray, Jessica,&Gu, Ying.(2021).Provenance of Fe in Chinese Deserts: Evidence from the geochemistry and mineralogy of soil particles.CATENA,198,9.
MLA He, Tong,et al."Provenance of Fe in Chinese Deserts: Evidence from the geochemistry and mineralogy of soil particles".CATENA 198(2021):9.
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