Water-Insoluble Organics Dominate Brown Carbon in Wintertime Urban Aerosol of China: Chemical Characteristics and Optical Properties

doi:10.1021/acs.est.0c01149

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	Water-Insoluble Organics Dominate Brown Carbon in Wintertime Urban Aerosol of China: Chemical Characteristics and Optical Properties
	Huang, Ru-Jin 1,2,3,4; Yang, Lu 1,2; Shen, Jincan 5; Yuan, Wei 1,2; Gong, Yuquan 1,2; Guo, Jie 1,2; Cao, Wenjuan 1,2; Duan, Jing 1,2; Ni, Haiyan 1,2,6; Zhu, Chongshu 1,2; Dai, Wenting 1,2; Li, Yongjie 7; Chen, Yang 8; Chen, Qi 9; Wu, Yunfei 10; Zhang, Renjian 10; Dusek, Ulrike 6; O'Dowd, Colin 11,12; Hoffmann, Thorsten 13
通讯作者	Huang, Ru-Jin(rujin.huang@ieecas.cn) ; Shen, Jincan(jincansh@263.net)
	2020-07-07
发表期刊	ENVIRONMENTAL SCIENCE & TECHNOLOGY
ISSN	0013-936X
卷号	54 期号:13 页码:7836-7847
摘要	The chromophores responsible for light absorption in atmospheric brown carbon (BrC) are not well characterized, which hinders our understanding of BrC chemistry, the links with optical properties, and accurate model representations of BrC to global climate and atmospheric oxidative capacity. In this study, the light absorption properties and chromophore composition of three BrC fractions of different polarities were characterized for urban aerosol collected in Xi'an and Beijing in winter 2013-2014. These three BrC fractions show large differences in light absorption and chromophore composition, but the chromophores responsible for light absorption are similar in Xi'an and Beijing. Water-insoluble BrC (WI-BrC) fraction dominates the total BrC absorption at 365 nm in both Xi'an (51 +/- 5%) and Beijing (62 +/- 13%), followed by a humic-like fraction (HULIS-BrC) and high-polarity water-soluble BrC. The major chromophores identified in HULIS-BrC are nitrophenols and carbonyl oxygenated polycyclic aromatic hydrocarbons (OPAHs) with 2-3 aromatic rings (in total 18 species), accounting for 10% and 14% of the light absorption of HULIS-BrC at 365 nm in Xi'an and Beijing, respectively. In comparison, the major chromophores identified in WI-BrC are PAHs and OPAHs with 4-6 aromatic rings (in total 16 species), contributing 6% and 8% of the light absorption of WI-BrC at 365 nm in Xi'an and Beijing, respectively.
DOI	10.1021/acs.est.0c01149
关键词[WOS]	LIGHT-ABSORPTION PROPERTIES ; POLYCYCLIC AROMATIC-HYDROCARBONS ; FINE PARTICULATE MATTER ; BLACK CARBON ; MOLECULAR CHARACTERIZATION ; EMISSION FACTORS ; OXYGENATED-PAHS ; MASS ; PM2.5 ; ATMOSPHERE
收录类别	SCI ; SCI
语种	英语
资助项目	National Natural Science Foundation of China (NSFC)[41877408] ; National Natural Science Foundation of China (NSFC)[41925015] ; National Natural Science Foundation of China (NSFC)[91644219] ; National Natural Science Foundation of China (NSFC)[41675120] ; Chinese Academy of Sciences[ZDBS-LY-DQC001] ; National Key Research and Development Program of China[2017YFC0212701] ; Cross Innovative Team fund from the State Key Laboratory of Loess and Quaternary Geology[SKLLQGTD1801]
WOS研究方向	Engineering ; Environmental Sciences & Ecology
项目资助者	National Natural Science Foundation of China (NSFC) ; Chinese Academy of Sciences ; National Key Research and Development Program of China ; Cross Innovative Team fund from the State Key Laboratory of Loess and Quaternary Geology
WOS类目	Engineering, Environmental ; Environmental Sciences
WOS记录号	WOS:000548584900015
出版者	AMER CHEMICAL SOC
引用统计	被引频次：65[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.ieecas.cn/handle/361006/15064
专题	粉尘与环境研究室第四纪科学与全球变化卓越创新中心
通讯作者	Huang, Ru-Jin; Shen, Jincan
作者单位	1.Chinese Acadcmy Sci, State Key Lab Loess & Quaternary Geol, Ctr Excellence Quaternary Sci & Global Change, Xian 710061, Peoples R China 2.Chinese Acadcmy Sci, Inst Earth Environm, Key Lab Aerosol Chem & Phys, Xian 710061, Peoples R China 3.Xi An Jiao Tong Univ, Inst Global Environm Change, Xian 710049, Peoples R China 4.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Ocean Continental Climate & Environm, Qingdao 266061, Peoples R China 5.Food Inspect & Quarantine Technol Ctr Shenzhen Cu, Key Lab Detect Technol R&D Food Safety, Shenzhen 518045, Peoples R China 6.Univ Groningen, Energy & Sustainabil Res Inst Groningen ESRIG, Ctr Isotope Res CIO, NL-9747 AG Groningen, Netherlands 7.Univ Macau, Fac Sci & Technol, Dept Civil & Environm Engn, Taipa 999078, Macao, Peoples R China 8.Chinese Acad Sci, Chongqing Inst Green & Intelligent Technol, Chongqing 400714, Peoples R China 9.Peking Univ, Coll Environm Sci & Engn, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100871, Peoples R China 10.Chinese Acad Sci, Inst Atmospher Phys, RCE TEA, Beijing 100029, Peoples R China 11.Natl Univ Ireland Galway, Sch Phys, Galway H91 CF50, Ireland 12.Natl Univ Ireland Galway, Ctr Climate & Air Pollut Studies, Ryan Inst, Galway H91 CF50, Ireland 13.Johannes Gutenberg Univ Mainz, Inst Inorgan & Analyt Chem, D-55128 Mainz, Germany
推荐引用方式 GB/T 7714	Huang, Ru-Jin,Yang, Lu,Shen, Jincan,et al. Water-Insoluble Organics Dominate Brown Carbon in Wintertime Urban Aerosol of China: Chemical Characteristics and Optical Properties[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2020,54(13):7836-7847.
APA	Huang, Ru-Jin.,Yang, Lu.,Shen, Jincan.,Yuan, Wei.,Gong, Yuquan.,...&Hoffmann, Thorsten.(2020).Water-Insoluble Organics Dominate Brown Carbon in Wintertime Urban Aerosol of China: Chemical Characteristics and Optical Properties.ENVIRONMENTAL SCIENCE & TECHNOLOGY,54(13),7836-7847.
MLA	Huang, Ru-Jin,et al."Water-Insoluble Organics Dominate Brown Carbon in Wintertime Urban Aerosol of China: Chemical Characteristics and Optical Properties".ENVIRONMENTAL SCIENCE & TECHNOLOGY 54.13(2020):7836-7847.