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Investigation of Primary and Secondary Particulate Brown Carbon in Two Chinese Cities of Xi'an and Hong Kong in Wintertime
Zhang, Qian1,3; Shen, Zhenxing1,2; Zhang, Leiming4; Zeng, Yaling1; Ning, Zhi5; Zhang, Tian1; Lei, Yali1; Wang, Qiyuan2; Li, Guohui2; Sun, Jian1; Westerdahl, Dane5; Xu, Hongmei1; Cao, Junji2
通讯作者Shen, Zhenxing(zxshen@mail.xjtu.edu.cn)
2020-04-07
发表期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
ISSN0013-936X
卷号54期号:7页码:3803-3813
摘要Brown carbon (BrC), an aerosol carbonaceous matter component, impacts atmospheric radiation and global climate because of its absorption in the near-ultraviolet-visible region. Simultaneous air sampling was conducted in two megacities of Xi'an (northern) and Hong Kong (southern) in China in winter of 2016-2017. The aim of this study is to determine and characterize the BrC compounds in collected filter samples. Characteristic absorption peaks corresponding to aromatic C-C stretching bands, organo-nitrates, and C=O functional groups were seen in spectra of Xi'an samples, suggesting that the BrC was derived from freshly smoldering biomass and coal combustion as well as aqueous formation of anthropogenic secondary organic carbon. In Hong Kong, the light absorption of secondary BrC accounted for 76% of the total absorbances of BrC. The high abundance of strong C=O groups, biogenic volatile organic compounds (BVOCs) and atmospheric oxidants suggest secondary BrC was likely formed from photochemical oxidation of BVOCs in Hong Kong. Several representative BrC molecular markers were detected using Fourier transform ion cyclotron resonance mass spectrometry and their absorption properties were simulated by quantum chemistry. The results demonstrate that light absorption capacities of secondary anthropogenic BrC with nitro-functional groups were stronger than those of biogenic secondary BrC and anthropogenic primary BrC.
DOI10.1021/acs.est.9b05332
关键词[WOS]MASS ABSORPTION EFFICIENCY ; COMPLEX REFRACTIVE-INDEXES ; ORGANIC FUNCTIONAL-GROUPS ; HUMIC-LIKE SUBSTANCES ; LIGHT-ABSORPTION ; BLACK CARBON ; OPTICAL-PROPERTIES ; AEROSOL FORMATION ; GUANZHONG PLAIN ; URBAN AEROSOLS
收录类别SCI ; SCI
语种英语
资助项目National Natural Science Foundation of China[41877383] ; National Natural Science Foundation of China[21661132005] ; National Natural Science Foundation of China[41573101] ; Natural Science Basic Research Plan in Shaanxi Province of China[2019JQ-177] ; China Postdoctoral Science Foundation[2018M643595] ; Key Research and Development Program of Shaanxi Province[2018-ZDXM3-01] ; Research Grants Council of the Hong Kong Special Administrative Region, China (RGC)[21201214]
WOS研究方向Engineering ; Environmental Sciences & Ecology
项目资助者National Natural Science Foundation of China ; Natural Science Basic Research Plan in Shaanxi Province of China ; China Postdoctoral Science Foundation ; Key Research and Development Program of Shaanxi Province ; Research Grants Council of the Hong Kong Special Administrative Region, China (RGC)
WOS类目Engineering, Environmental ; Environmental Sciences
WOS记录号WOS:000526418000011
出版者AMER CHEMICAL SOC
引用统计
被引频次:57[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ieecas.cn/handle/361006/14706
专题粉尘与环境研究室
通讯作者Shen, Zhenxing
作者单位1.Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian 710049, Peoples R China
2.Chinese Acad Sci, Inst Earth Environm, Key Lab Aerosol Chem & Phys, SKLLQG, Xian, Peoples R China
3.Xian Univ Architecture & Technol, Key Lab Northwest Resource Environm & Ecol, MOE, Xian 710055, Peoples R China
4.Environm & Climate Change Canada, Sci & Technol Branch, Air Qual Res Div, Toronto, ON, Canada
5.Hong Kong Univ Sci & Technol, Div Environm & Sustainabil, Hong Kong, Peoples R China
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Zhang, Qian,Shen, Zhenxing,Zhang, Leiming,et al. Investigation of Primary and Secondary Particulate Brown Carbon in Two Chinese Cities of Xi'an and Hong Kong in Wintertime[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2020,54(7):3803-3813.
APA Zhang, Qian.,Shen, Zhenxing.,Zhang, Leiming.,Zeng, Yaling.,Ning, Zhi.,...&Cao, Junji.(2020).Investigation of Primary and Secondary Particulate Brown Carbon in Two Chinese Cities of Xi'an and Hong Kong in Wintertime.ENVIRONMENTAL SCIENCE & TECHNOLOGY,54(7),3803-3813.
MLA Zhang, Qian,et al."Investigation of Primary and Secondary Particulate Brown Carbon in Two Chinese Cities of Xi'an and Hong Kong in Wintertime".ENVIRONMENTAL SCIENCE & TECHNOLOGY 54.7(2020):3803-3813.
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