粉尘与环境研究室知识库

The implementation of the Air Pollution Prevention and Control Action Plan in China since 2013 has profoundly altered the ambient pollutants in the Beijing-Tianjin-Hebei (BTH) region. Here we show observations of substantially increased O-3 concentrations (about 30 %) and a remarkable increase in the ratio of organic carbon (OC) to elemental carbon (EC) in BTH during the autumn from 2013 to 2015, revealing an enhancement in atmospheric oxidizing capacity (AOC) and secondary organic aerosol (SOA) formation. To explore the impacts of increasing AOC on the SOA formation, a severe air pollution episode from 3 to 8 October 2015 with high O-3 and PM2.5 concentrations is simulated using the WRF-Chem model. The model performs reasonably well in simulating the spatial distributions of PM2.5 and O-3 concentrations over BTH and the temporal variations in PM2.5, O-3, NO2, OC, and EC concentrations in Beijing compared to measurements. Sensitivity studies show that the change in AOC substantially influences the SOA formation in BTH. A sensitivity case characterized by a 31 % 03 decrease (or 36 % OH decrease) reduces the SOA level by about 30 % and the SOA fraction in total organic aerosol by 17 % (from 0.52 to 0.43, dimensionless). Spatially, the SOA decrease caused by reduced AOC is ubiquitous in BTH, but the spatial relationship between SOA concentrations and the AOC is dependent on the SOA precursor distribution. Studies on SOA formation pathways further show that when the AOC is reduced, the SOA from oxidation and partitioning of semivolatile primary organic aerosol (POA) and coemitted intermediate volatile organic compounds (IVOCs) decreases remarkably, followed by those from anthropogenic and biogenic volatile organic compounds (VOCs). Meanwhile, the SOA decrease in the irreversible uptake of glyoxal and methylglyoxal on the aerosol surfaces is negligible.