Seasonal characteristics of biogenic secondary organic aerosols at Mt. Wuyi in Southeastern China: Influence of anthropogenic pollutants

doi:10.1016/j.envpol.2019.05.077

IEECAS OpenIR > 粉尘与环境研究室

	Seasonal characteristics of biogenic secondary organic aerosols at Mt. Wuyi in Southeastern China: Influence of anthropogenic pollutants
	Ren, Yanqin 1,2; Wang, Gehui 2,3; Tao, Jun 4; Zhang, Zhisheng 4; Wu, Can 2,3; Wang, Jiayuan 2; Li, Jianjun 2; Wei, Jie 5; Li, Hong 1; Meng, Fan 1
通讯作者	Wang, Gehui(ghwang@geo.ecnu.edu.cn)
	2019-09-01
发表期刊	ENVIRONMENTAL POLLUTION
ISSN	0269-7491
卷号	252 页码:493-500
摘要	Thirteen secondary organic aerosol (SOA) tracers of isoprene, monoterpenes and sesquiterpenes were measured for PM2.5 aerosols collected at the summit of Mt. Wuyi (1139 m, a.s.l.), to investigate their seasonality and formation mechanism. Concentrations of the isoprene and monoterpene SOA tracers were much higher in summer than those in other seasons. In contrast, beta-caryophyllinic acid was found to be the lowest in summer. Concentrations of those BSOA tracers showed a positive correlation with temperature (R-2 = 0.52-0.70), and a negative correlation with relative humidity (R-2 = 0.43-0.78). Moreover, thermodynamic model (i.e., ISORROPIA-II) calculation results showed that acidity conditions are favorable for BSOA formation. Robust linear correlations between the BSOA tracers and anthropogenic pollutants such as SO2 (R-2 = 0.53-0.7) and NO2 (R-2 = 037-0.54) were observed for all the samples, suggesting that SO2 and NOx can enhance BSOA production in the remote mountain area of southeast China, which is related to an acid-catalyzed heterogeneous chemistry. Moreover, we also found a significant correlation between the concentrations of the BSOA tracers and levoglucosan especially for beta-caryophyllinic acid, indicating that biomass burning plumes from the distant lowland regions could influence the production of BSOA in the mountain free troposphere. Our results clearly demonstrated that anthropogenic emissions in China could enhance BSOA formation in the distant mountain regions. (C) 2019 Elsevier Ltd. All rights reserved.
关键词	Secondary organic aerosol Isoprene Monoterpene beta-Caryophyllene Anthropogenic pollutants Biomass burning
DOI	10.1016/j.envpol.2019.05.077
关键词[WOS]	PINENE OXIDATION-PRODUCTS ; 2013 SOUTHERN OXIDANT ; ATMOSPHERIC AEROSOLS ; SIZE DISTRIBUTION ; AIR-QUALITY ; EAST CHINA ; ISOPRENE ; PM2.5 ; SITE ; PHOTOOXIDATION
收录类别	SCI ; SCI
语种	英语
资助项目	National Key RD Plan[2017YFC0210000] ; China National Natural Science Funds for Distinguished Young Scholars[41325014] ; National Natural Science Foundation of China[41773117]
WOS研究方向	Environmental Sciences & Ecology
项目资助者	National Key RD Plan ; China National Natural Science Funds for Distinguished Young Scholars ; National Natural Science Foundation of China
WOS类目	Environmental Sciences
WOS记录号	WOS:000483005500052
出版者	ELSEVIER SCI LTD
引用统计	被引频次：31[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.ieecas.cn/handle/361006/13396
专题	粉尘与环境研究室
通讯作者	Wang, Gehui
作者单位	1.Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Beijing 100012, Peoples R China 2.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian 710061, Shaanxi, Peoples R China 3.East China Normal Univ, Sch Geog Sci, Minist Educ China, Key Lab Geog Informat Sci, Shanghai 200142, Peoples R China 4.Minist Ecol & Environm, South China Inst Environm Sci, Guangzhou 510655, Guangdong, Peoples R China 5.Chinese Acad Sci, Key Lab Ecosyst Network Observat & Modeling, Inst Geog Sci & Nat Resources Res, Beijing 100101, Peoples R China
推荐引用方式 GB/T 7714	Ren, Yanqin,Wang, Gehui,Tao, Jun,et al. Seasonal characteristics of biogenic secondary organic aerosols at Mt. Wuyi in Southeastern China: Influence of anthropogenic pollutants[J]. ENVIRONMENTAL POLLUTION,2019,252:493-500.
APA	Ren, Yanqin.,Wang, Gehui.,Tao, Jun.,Zhang, Zhisheng.,Wu, Can.,...&Meng, Fan.(2019).Seasonal characteristics of biogenic secondary organic aerosols at Mt. Wuyi in Southeastern China: Influence of anthropogenic pollutants.ENVIRONMENTAL POLLUTION,252,493-500.
MLA	Ren, Yanqin,et al."Seasonal characteristics of biogenic secondary organic aerosols at Mt. Wuyi in Southeastern China: Influence of anthropogenic pollutants".ENVIRONMENTAL POLLUTION 252(2019):493-500.