| Predominance of secondary organic aerosol to particle-bound reactive oxygen species activity in fine ambient aerosol | |
| Zhou, Jun1,7; Elser, Miriam1,8; Huang, Ru-Jin1,2; Krapf, Manuel1; Frohlich, Roman1; Bhattu, Deepika1; Stefenelli, Giulia1; Zotter, Peter3; Bruns, Emily A.1; Pieber, Simone M.1,9; Ni, Haiyan2; Wang, Qiyuan2; Wang, Yichen2; Zhou, Yaqing2; Chen, Chunying4; Xiao, Mao1; Slowik, Jay G.1; Brown, Samuel1,5; Cassagnes, Laure-Estelle1; Daellenbach, Kaspar R.1,10; Nussbaumer, Thomas3; Geiser, Marianne6; Prevot, Andre S. H.1; El-Haddad, Imad1; Cao, Junji2; Baltensperger, Urs1; Dommen, Josef1 | |
| Corresponding Author | Huang, Ru-Jin(rujin.huang@ieecas.cn) ; Dommen, Josef(josef.dommen@psi.ch) |
| 2019-12-05 | |
| Source Publication | ATMOSPHERIC CHEMISTRY AND PHYSICS
 |
| ISSN | 1680-7316 |
| Volume | 19Issue:23Pages:14703-14720 |
| Abstract | Reactive oxygen species (ROS) are believed to contribute to the adverse health effects of aerosols. This may happen by inhaled particle-bound (exogenic) ROS (PB-ROS) or by ROS formed within the respiratory tract by certain aerosol components (endogenic ROS). We investigated the chemical composition of aerosols and their exogenic ROS content at the two contrasting locations Beijing (China) and Bern (Switzerland). We apportioned the ambient organic aerosol to different sources and attributed the observed water-soluble PB-ROS to them. The oxygenated organic aerosol (OOA, a proxy for secondary organic aerosol, SOA) explained the highest fraction of the exogenic ROS concentration variance at both locations. We also characterized primary and secondary aerosol emissions generated from different biogenic and anthropogenic sources in smog chamber experiments. The exogenic PB-ROS content in the OOA from these emission sources was comparable to that in the ambient measurements. Our results imply that SOA from gaseous precursors of different anthropogenic emission sources is a crucial source of water-soluble PB-ROS and should be additionally considered in toxicological and epidemiological studies in an adequate way besides primary emissions. The importance of PB-ROS may be connected to the seasonal trends in health effects of PM reported by epidemiological studies, with elevated incidences of adverse effects in warmer seasons, which are accompanied by more-intense atmospheric oxidation processes. |
| DOI | 10.5194/acp-19-14703-2019 |
| WOS Keyword | PARTICULATE AIR-POLLUTION ; POSITIVE MATRIX FACTORIZATION ; STRESS-RESPONSE GENES ; WATER-SOLUBLE PM2.5 ; EXTENDED FOLLOW-UP ; SOURCE APPORTIONMENT ; DAILY MORTALITY ; GAS-PHASE ; CHEMICAL-COMPOSITION ; MASS-SPECTROMETRY |
| Indexed By | SCI ; SCI |
| Language | 英语 |
| Funding Project | Swiss National Science Foundation[CR32I3-140851] ; Swiss National Science Foundation[CR32I3_166325] ; Swiss National Science Foundation[200021L_140590] ; Swiss National Science Foundation[BSSGI0_155846] ; Swiss National Science Foundation (NRP 70 Energy Turnaround) ; European Union[730997] ; National Natural Science Foundation of China[91644219] ; National Natural Science Foundation of China[21661132005] ; National Key Research and Development Program of China[2017YFC0212701] ; China Scholarship Council[201307040040] ; Sino-Swiss Science Technology Cooperation (SSSTC) project HAZECHINA (Haze pollution in China: Sources and atmospheric evolution of particulate matter)[IZLCZ2_169986] ; Swiss Innovation Agency Innosuisse (SCCER BIOSWEET) |
| WOS Research Area | Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences |
| Funding Organization | Swiss National Science Foundation ; Swiss National Science Foundation (NRP 70 Energy Turnaround) ; European Union ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; China Scholarship Council ; Sino-Swiss Science Technology Cooperation (SSSTC) project HAZECHINA (Haze pollution in China: Sources and atmospheric evolution of particulate matter) ; Swiss Innovation Agency Innosuisse (SCCER BIOSWEET) |
| WOS Subject | Environmental Sciences ; Meteorology & Atmospheric Sciences |
| WOS ID | WOS:000501517100002 |
| Publisher | COPERNICUS GESELLSCHAFT MBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.ieecas.cn/handle/361006/13071 |
| Collection | 粉尘与环境研究室 |
| Corresponding Author | Huang, Ru-Jin; Dommen, Josef |
| Affiliation | 1.Paul Scherrer Inst, Lab Atmospher Chem, CH-5232 Villigen, Switzerland 2.Chinese Acad Sci, Inst Earth Environm, Xian 710061, Shaanxi, Peoples R China 3.Lucerne Univ Appl Sci & Arts, Bioenergy Res Grp, Engn & Architecture, CH-6048 Horw, Switzerland 4.Chinese Acad Sci, Key Lab Biol Effects Nanomat & Nanosafety, Natl Ctr Nanosci & Technol, Beijing 100191, Peoples R China 5.ETH, Inst Atmospher & Climate Sci, CH-8092 Zurich, Switzerland 6.Univ Bern, Inst Anat, CH-3012 Bern, Switzerland 7.Kyoto Univ, Grad Sch Global Environm Studies, Kyoto 6068501, Japan 8.Empa, Automot Powertrain Technol, CH-8600 Dubendorf, Switzerland 9.Empa, Lab Air Pollut Environm Technol, CH-8600 Dubendorf, Switzerland 10.Univ Helsinki, Fac Sci, Inst Atmospher & Earth Syst Res, FIN-00014 Helsinki, Finland |
| Recommended Citation GB/T 7714 | Zhou, Jun,Elser, Miriam,Huang, Ru-Jin,et al. Predominance of secondary organic aerosol to particle-bound reactive oxygen species activity in fine ambient aerosol[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2019,19(23):14703-14720. |
| APA | Zhou, Jun.,Elser, Miriam.,Huang, Ru-Jin.,Krapf, Manuel.,Frohlich, Roman.,...&Dommen, Josef.(2019).Predominance of secondary organic aerosol to particle-bound reactive oxygen species activity in fine ambient aerosol.ATMOSPHERIC CHEMISTRY AND PHYSICS,19(23),14703-14720. |
| MLA | Zhou, Jun,et al."Predominance of secondary organic aerosol to particle-bound reactive oxygen species activity in fine ambient aerosol".ATMOSPHERIC CHEMISTRY AND PHYSICS 19.23(2019):14703-14720. |
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