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Radical Formation by Fine Particulate Matter Associated with Highly Oxygenated Molecules
Tong, Haijie1; Zhang, Yun2; Filippi, Alexander1; Wang, Ting1,3; Li, Chenpei1,3; Liu, Fobang1,4; Leppla, Denis2; Kourtchev, Ivan5; Wang, Kai2,22; Keskinen, Helmi-Marja6; Levula, Janne T.6; Arangio, Andrea M.1,7; Shen, Fangxia8; Ditas, Florian1; Martin, Scot T.9,10; Artaxo, Paulo11; Godoi, Ricardo H. M.12; Yamamoto, Carlos I.13; de Souza, Rodrigo A. F.14; Huang, Ru-Jin15; Berkemeier, Thomas1; Wang, Yueshe3; Su, Hang1; Cheng, Yafang1; Pope, Francis D.16; Fu, Pingqing17; Yao, Maosheng18; Poehlker, Christopher1; Petaja, Tuukka6; Kulmala, Markku6; Andreae, Meinrat O.1,19; Shiraiwa, Manabu20; Poeschl, Ulrich1; Hoffmann, Thorsten2; Kalberer, Markus5,21
通讯作者Tong, Haijie(h.tong@mpic.de) ; Hoffmann, Thorsten(hoffmant@uni-mainz.de) ; Kalberer, Markus(markus.kalberer@unibas.ch)
2019-11-05
发表期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
ISSN0013-936X
卷号53期号:21页码:12506-12518
摘要Highly oxygenated molecules (HOMs) play an important role in the formation and evolution of secondary organic aerosols (SOA). However, the abundance of HOMs in different environments and their relation to the oxidative potential of fine particulate matter (PM) are largely unknown. Here, we investigated the relative HOM abundance and radical yield of laboratory-generated SOA and fine PM in ambient air ranging from remote forest areas to highly polluted megacities. By electron paramagnetic resonance and mass spectrometric investigations, we found that the relative abundance of HOMs, especially the dimeric and low-volatility types, in ambient fine PM was positively correlated with the formation of radicals in aqueous PM extracts. SOA from photooxidation of isoprene, ozonolysis of alpha- and beta-pinene, and fine PM from tropical (central Amazon) and boreal (Hyytiala, Finland) forests exhibited a higher HOM abundance and radical yield than SOA from photooxidation of naphthalene and fine PM from urban sites (Beijing, Guangzhou, Mainz, Shanghai, and Xian), confirming that HOMs are important constituents of biogenic SOA to generate radicals. Our study provides new insights into the chemical relationship of HOM abundance, composition, and sources with the yield of radicals by laboratory and ambient aerosols, enabling better quantification of the component-specific contribution of source- or site-specific fine PM to its climate and health effects.
DOI10.1021/acs.est.9b05149
关键词[WOS]SECONDARY ORGANIC AEROSOL ; CHEMICAL-COMPOSITION ; OXIDIZED MOLECULES ; HYDROXYL RADICALS ; MULTIPHASE CHEMISTRY ; UPPER TROPOSPHERE ; MASS ; OXIDATION ; VOLATILITY ; MECHANISMS
收录类别SCI ; SCI
语种英语
资助项目Max Planck Society ; National Science Fund for Distinguished Young Scholars[41625014] ; Projects of International Cooperation and Exchanges NSFC[41571130024] ; Projects of International Cooperation and Exchanges NSFC[51576160] ; ACTRIS ; ECAC ; Finnish Centre of Excellence under Academy of Finland[307331] ; Finnish Centre of Excellence under Academy of Finland[272041] ; German Federal Ministry of Education and Research (BMBF)[01LB1001A] ; German Federal Ministry of Education and Research (BMBF)[01LK1602B] ; Brazilian Ministerio da Ciencia, Tecnologia e Inovacao (MCTI/FINEP)[01.11.01248.00] ; China Scholarship Council ; Deutscher Akademischer Austauschdienst (DAAD) ; Amazon State University (UEA) ; FAPEAM ; Central Office of the Large Scale Biosphere Atmosphere Experiment in Amazonia (LBA) ; National Institute of Amazonian Research (INPA) ; SDS/CEUC/RDS-Uatuma ; Atmospheric Radiation Measurement (ARM) Climate Research Facility, a user facility of the United States Department of Energy (DOE), Office of Science - Office of Biological and Environmental Research[DE-SC0006680] ; Brazilian National Council for Scientific and Technological Development (CNPq)[001030/2012-4] ; U.S. National Science Foundation[CHE-1808125] ; FAPESP[2017/17047-0]
WOS研究方向Engineering ; Environmental Sciences & Ecology
项目资助者Max Planck Society ; National Science Fund for Distinguished Young Scholars ; Projects of International Cooperation and Exchanges NSFC ; ACTRIS ; ECAC ; Finnish Centre of Excellence under Academy of Finland ; German Federal Ministry of Education and Research (BMBF) ; Brazilian Ministerio da Ciencia, Tecnologia e Inovacao (MCTI/FINEP) ; China Scholarship Council ; Deutscher Akademischer Austauschdienst (DAAD) ; Amazon State University (UEA) ; FAPEAM ; Central Office of the Large Scale Biosphere Atmosphere Experiment in Amazonia (LBA) ; National Institute of Amazonian Research (INPA) ; SDS/CEUC/RDS-Uatuma ; Atmospheric Radiation Measurement (ARM) Climate Research Facility, a user facility of the United States Department of Energy (DOE), Office of Science - Office of Biological and Environmental Research ; Brazilian National Council for Scientific and Technological Development (CNPq) ; U.S. National Science Foundation ; FAPESP
WOS类目Engineering, Environmental ; Environmental Sciences
WOS记录号WOS:000495467500039
出版者AMER CHEMICAL SOC
引用统计
被引频次:42[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ieecas.cn/handle/361006/12949
专题粉尘与环境研究室
通讯作者Tong, Haijie; Hoffmann, Thorsten; Kalberer, Markus
作者单位1.Max Planck Inst Chem, Multiphase Chem Dept, D-55128 Mainz, Germany
2.Johannes Gutenberg Univ Mainz, Inst Inorgan & Analyt Chem, D-55128 Mainz, Germany
3.Xi An Jiao Tong Univ, State Key Lab Multiphase Flow Power Engn, Xian 710049, Shaanxi, Peoples R China
4.Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
5.Univ Cambridge, Ctr Atmospher Sci, Dept Chem, Cambridge CB2 1EW, England
6.Univ Helsinki, Phys Fac Sci, Inst Atmospher & Earth Syst Res, FI-00014 Helsinki, Finland
7.Ecole Polytech Fed Lausanne, CH-1015 Lausanne, Switzerland
8.Beihang Univ, Sch Space & Environm, Beijing 100191, Peoples R China
9.Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA
10.Harvard Univ, Dept Earth & Planetary Sci, Cambridge, MA 02138 USA
11.Univ Sao Paulo, Phys Inst, BR-05508900 Sao Paulo, Brazil
12.Univ Fed Parana, Environm Engn Dept, BR-81531980 Curitiba, Parana, Brazil
13.Univ Fed Parana, Chem Engn Dept, BR-81531970 Curitiba, Parana, Brazil
14.Amazonas State Univ, Sch Technol, BR-69065020 Manaus, Amazonas, Brazil
15.Chinese Acad Sci, Inst Earth & Environm, State Key Lab Loess & Quaternary Geol, Key Lab Aerosol Chem & Phys, Xian 710061, Shaanxi, Peoples R China
16.Univ Birmingham, Sch Geog Earth & Environm Sci, Birmingham B15 2TT, W Midlands, England
17.Tianjin Univ, Inst Surface Earth Syst Sci, Tianjin 300072, Peoples R China
18.Peking Univ, Coll Environm Sci & Engn, Beijing 100871, Peoples R China
19.Univ Calif San Diego, Scripps Inst Oceanog, San Diego, CA 92093 USA
20.Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
21.Univ Basel, Dept Environm Sci, Klingelbergstr 27, CH-4056 Basel, Switzerland
22.Aarhus Univ, Dept Chem, Langelandsgade 140, DK-8000 Aarhus, Denmark
推荐引用方式
GB/T 7714
Tong, Haijie,Zhang, Yun,Filippi, Alexander,et al. Radical Formation by Fine Particulate Matter Associated with Highly Oxygenated Molecules[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2019,53(21):12506-12518.
APA Tong, Haijie.,Zhang, Yun.,Filippi, Alexander.,Wang, Ting.,Li, Chenpei.,...&Kalberer, Markus.(2019).Radical Formation by Fine Particulate Matter Associated with Highly Oxygenated Molecules.ENVIRONMENTAL SCIENCE & TECHNOLOGY,53(21),12506-12518.
MLA Tong, Haijie,et al."Radical Formation by Fine Particulate Matter Associated with Highly Oxygenated Molecules".ENVIRONMENTAL SCIENCE & TECHNOLOGY 53.21(2019):12506-12518.
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