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Sources and a proposal for comprehensive exploitation of lithium brine deposits in the Qaidam Basin on the northern Tibetan Plateau, China: Evidence from Li isotopes
He, Mao-Yong1,2,4; Luo, Chong-Guang3; Yang, Hong-Jun5,6; Kong, Fan-Cui5,7; Li, Yu-Long5,7; Deng, Li1,9; Zhang, Xi-Ying5,7; Yang, Kai-Yuan8
通讯作者He, Mao-Yong(hemy@ieecas.cn) ; Yang, Hong-Jun(hjyang@isl.ac.cn)
2020-02-01
发表期刊ORE GEOLOGY REVIEWS
ISSN0169-1368
卷号117页码:7
摘要A thorough understanding of the origin and distribution of lithium brine deposits is the foundation for lithium resource exploration, development and utilization. The lithium isotope system, a sensitive geochemical tracer, can be used to track a wide range of geological processes and sources. This study investigates major cations, [Li], and delta Li-7 of samples (brine lakes, intercrystalline brines, river waters, rain, hot spring waters, spring waters and rocks) from the Qaidam Basin on the northern Tibetan Plateau, China. [Li] values vary from less than 0.01 mg L-1 to similar to 408.83 mg L-1. There are significant differences in [Li] for different sample types. spring water (rain) < river samples < brine lakes < intercrystalline brines. The delta Li-7 values of samples display as significant variations as [Li], ranging from 4.33 parts per thousand to +40.66 parts per thousand. There are also significant differences in delta Li-7 for different sample types. The delta Li-7 values of spring water and river waters are relatively low and the values are from 4.33 parts per thousand to 18.37 parts per thousand. However, intercrystalline brines and saline lakes have the higher values, and the heaviest delta Li-7 (+40.66 parts per thousand) occurs in Chaka Lake. The delta Li-7 values in brine lakes in the Qaidam Basin show obvious regional distributions, which are also consistent with the structural characteristics of the Qaidam Basin. The possible sources of lithium in the brine lakes of the Qaidam Basin result from multiple mixing of redissolved Li from earlier salt sediments, deep groundwater via fractures (oil field brines, hot springs, etc.), low-temperature weathering processes of Li-rich rock, and freshwater. The results suggest that delta Li-7 should be a powerful tracer to unravel the sources of Li and reconstruct its accumulation processes in brine lakes. This study provides important theoretical and practical guidance for the effective protection of precious lithium brine deposits and sustainable lithium resource exploration.
关键词Lithium isotopic composition Lithium brine deposit Source and distribution Qaidam Basin
DOI10.1016/j.oregeorev.2019.103277
关键词[WOS]SALT LAKE ; ORIGIN ; SYSTEM ; BORON ; GEOCHEMISTRY ; GROUNDWATERS ; CONSTRAINTS ; EXTRACTION ; ENRICHMENT ; ALTIPLANO
收录类别SCI ; SCI
语种英语
资助项目National Natural Science Foundation of China[41573013] ; Second Tibetan Plateau Scientific Expedition and Research[2019QZKK0707] ; Qinghai Province State People's Government[U1407109] ; Qinghai Province State People's Government[U1707601] ; Applied Basic Research Program of Qinghai Province[2019-ZJ-7004] ; NSFC[U1407109] ; NSFC[U1707601]
WOS研究方向Geology ; Mineralogy ; Mining & Mineral Processing
项目资助者National Natural Science Foundation of China ; Second Tibetan Plateau Scientific Expedition and Research ; Qinghai Province State People's Government ; Applied Basic Research Program of Qinghai Province ; NSFC
WOS类目Geology ; Mineralogy ; Mining & Mineral Processing
WOS记录号WOS:000515206900042
出版者ELSEVIER
引用统计
被引频次:59[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ieecas.cn/handle/361006/12746
专题加速器质谱中心
第四纪科学与全球变化卓越创新中心
通讯作者He, Mao-Yong; Yang, Hong-Jun
作者单位1.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian 710061, Peoples R China
2.Chinese Acad Sci, Ctr Excellence Quaternary Sci & Global Change, Xian 710061, Peoples R China
3.Chinese Acad Sci, Inst Geochem, State Key Lab Ore Deposit Geochem, Guiyang 550002, Peoples R China
4.Univ Washington, Dept Earth & Space Sci, Isotope Lab, Seattle, WA 98195 USA
5.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Peoples R China
6.Key Lab Salt Lake Resources Chem Qinghai Prov, Xining, Peoples R China
7.Qinghai Prov Key Lab Geol & Environm Salt Lake, Xining 810008, Peoples R China
8.Changan Univ, Xian 710054, Peoples R China
9.Shaanxi Key Lab Accelerator Mass Spectrometry Tec, Xian 710061, Peoples R China
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He, Mao-Yong,Luo, Chong-Guang,Yang, Hong-Jun,et al. Sources and a proposal for comprehensive exploitation of lithium brine deposits in the Qaidam Basin on the northern Tibetan Plateau, China: Evidence from Li isotopes[J]. ORE GEOLOGY REVIEWS,2020,117:7.
APA He, Mao-Yong.,Luo, Chong-Guang.,Yang, Hong-Jun.,Kong, Fan-Cui.,Li, Yu-Long.,...&Yang, Kai-Yuan.(2020).Sources and a proposal for comprehensive exploitation of lithium brine deposits in the Qaidam Basin on the northern Tibetan Plateau, China: Evidence from Li isotopes.ORE GEOLOGY REVIEWS,117,7.
MLA He, Mao-Yong,et al."Sources and a proposal for comprehensive exploitation of lithium brine deposits in the Qaidam Basin on the northern Tibetan Plateau, China: Evidence from Li isotopes".ORE GEOLOGY REVIEWS 117(2020):7.
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