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Mass spectrometric determination of the special parameters of the potassium-calcium isotopic system | |
Peng, ZC; Wang, JX; Zhang, X; Liu, GJ; He, JF | |
2002-11 | |
发表期刊 | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY |
卷号 | 30期号:11页码:1281-1284 |
文章类型 | Article |
摘要 | The K-40 similar to Ca-40 isotopic system is important to be used in the geochronology and trace geochemistry. The Ca-40/Ca-42 isotopic ratios and the Ca contents in the CaO reagent and Tahite standard have been determined by using the isotopic dilution mehtod and the Finnigan MAT-262 mass spectrometer. The Ca-40/Ca-42 ratios is 151.43 +/- 0.03 (n = 7) ( standard value: 151.47 +/- 0.03 (n = 5)), while the Ca-40 content in Tahiti is 2.036 +/- 0.003 mumol/g (n = 5) and its relative error between the measured and certified values is +/- 0.13%. The isotopic abundance of K-39, K-40 and K-41 in the national K standard is 0.93260 +/- 0.00012, 0.0001120 +/- 0.0000129 and 0.067286 +/- 0.000125, respectively. The K-39/K-41 ratio of the stable isotopes is 13.860 +/- 0.027 (n = 5), which is consistent to the value of 13.857 +/- 0.006 in the NIST-SRM985 international standard. the precise determination of the special parameters in the K-Ca system is the foundation of timing and tracing study in the future time. |
关键词 | potassium-calcium standard potassium-calcium isotopic system mass spectrometry |
学科领域 | Chemistry |
收录类别 | SCI ; SCIE |
语种 | 中文 |
WOS研究方向 | Chemistry, Analytical |
WOS记录号 | WOS:000179713000001 |
出版者 | SCIENCE CHINA PRESS |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.ieecas.cn/handle/361006/12110 |
专题 | 黄土与第四纪地质国家重点实验室(1985-2004) |
推荐引用方式 GB/T 7714 | Peng, ZC,Wang, JX,Zhang, X,et al. Mass spectrometric determination of the special parameters of the potassium-calcium isotopic system[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2002,30(11):1281-1284. |
APA | Peng, ZC,Wang, JX,Zhang, X,Liu, GJ,&He, JF.(2002).Mass spectrometric determination of the special parameters of the potassium-calcium isotopic system.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,30(11),1281-1284. |
MLA | Peng, ZC,et al."Mass spectrometric determination of the special parameters of the potassium-calcium isotopic system".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 30.11(2002):1281-1284. |
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