Effects of cone combinations on accurate and precise Mg-isotopic determination using multi-collector inductively coupled plasma mass spectrometry

doi:10.1002/rcm.8356

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	Effects of cone combinations on accurate and precise Mg-isotopic determination using multi-collector inductively coupled plasma mass spectrometry
	Gou, LF (Gou, Long-Fei)1,2,3; Jin, ZD (Jin, Zhangdong)1; Galy, A (Galy, Albert)2; Sun, H (Sun, He); Deng, L (Deng, Li)1; Xu, Y (Xu, Yang)1,3
通讯作者	Gou, Long-Fei(goulf@ieecas.cn)
	2019-02-28
发表期刊	RAPID COMMUNICATIONS IN MASS SPECTROMETRY
ISSN	0951-4198
卷号	33 期号:4 页码:351-360
产权排序	1
摘要	Rationale High-precision determination of magnesium (Mg) isotopes can now be routinely achieved by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). The analytical sensitivity and instrumental mass discrimination behavior of this method are, however, sensitive to the types of sample and skimmer cones used in these measurements, so it is important that these parameters should be investigated. Methods Using the sample-standard-bracketing method in the wet-plasma mode, four available combinations of sample and skimmer cones [Jet sample cone + H skimmer cone (Jet + H), standard sample cone + H skimmer cone (Standard + H), standard sample cone + X skimmer cone (Standard + X), and Jet sample cone + X skimmer cone (Jet + X)] were systematically investigated for peak shape, sensitivity, mass discrimination, accuracy, and precision in Mg-isotopic ratio determination using a Neptune plus MC-ICP mass spectrometer. Results The results showed that different cone combinations do not affect peak shapes but would significantly change the sensitivities for Mg-isotopic determinations. Compared with using the Standard + H, the sensitivities of Mg-isotopic determinations were enhanced by approximately a factor of 1.3, 1.4, and 1.9 by using the Standard + X, the Jet + H, and the Jet + X combinations, with the most stable mass discrimination behaviors obtained by the Jet + H. The instrumental mass fractionation slope for any combination of a modified cone geometry (i.e. Standard + X, Jet + X, and Jet + H) is 0.500, while it is 0.510 for the Standard + H. In addition, the mass discrimination behavior is related to Mg concentrations once the combination is set, indicating the necessity of concentration match during Mg-isotopic determination. Conclusions The precision and accuracy of the Jet + H combination are better than those of the other combinations, and this is further supported by the validation of the Mg-isotope data for four international reference materials: Cambridge-1, NASS-6, AGV-2, and BHVO-2. As the Jet + H combination also provides a high signal, this combination gives the most robust strategy for the highly precise and accurate determination of Mg isotopes.
DOI	10.1002/rcm.8356
关键词[WOS]	MC-ICP-MS ; ENHANCED SENSITIVITY ; MAGNESIUM ; FRACTIONATION ; RATIO ; GEOCHEMISTRY ; CARBONATE ; SKIMMER ; CA
收录类别	SCI ; SCIE
语种	英语
资助项目	National Natural Science Foundation of China[41773149] ; State Key Laboratory of Loess and Quaternary Geology[Y752YQ3443] ; Chinese Academy of Sciences[132B61KYSB20170008] ; Chinese Academy of Sciences[QYZDJ-SSW-DQC033]
WOS研究方向	Biochemistry & Molecular Biology ; Chemistry ; Spectroscopy
项目资助者	National Natural Science Foundation of China ; State Key Laboratory of Loess and Quaternary Geology ; Chinese Academy of Sciences
WOS类目	Biochemical Research Methods ; Chemistry, Analytical ; Spectroscopy
WOS记录号	WOS:000457242400004
出版者	WILEY
引用统计	被引频次：14[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.ieecas.cn/handle/361006/10944
专题	加速器质谱中心
通讯作者	Gou, LF (Gou, Long-Fei)
作者单位	1.Chinese Acad Sci, State Key Lab Loess & Quaternary Geol, Inst Earth Environm, Xian 710061, Peoples R China; 2.Univ Lorraine, CNRS, UMR7358, Ctr Rech Petrog & Geochim, F-54500 Vandoeuvre Les Nancy, France; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Gou, LF ,Jin, ZD ,Galy, A ,et al. Effects of cone combinations on accurate and precise Mg-isotopic determination using multi-collector inductively coupled plasma mass spectrometry[J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY,2019,33(4):351-360.
APA	Gou, LF ,Jin, ZD ,Galy, A ,Sun, H ,Deng, L ,&Xu, Y .(2019).Effects of cone combinations on accurate and precise Mg-isotopic determination using multi-collector inductively coupled plasma mass spectrometry.RAPID COMMUNICATIONS IN MASS SPECTROMETRY,33(4),351-360.
MLA	Gou, LF ,et al."Effects of cone combinations on accurate and precise Mg-isotopic determination using multi-collector inductively coupled plasma mass spectrometry".RAPID COMMUNICATIONS IN MASS SPECTROMETRY 33.4(2019):351-360.

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